1211 THE COLLIERY GUARDIAN. June 6, 1913. A RECORD OF THE ORIGIN OF THE PRINCIPLE OF STONEDUSTING FOR THE PREVENTION OF COLLIERY EXPLOSIONS.* By W. E. Garforth, LL.D., M.Inst.C.E. The author gives an account of the investigations that have been made in connection with the danger of coal du st in mines during the past five years, as well as an account of the further experiments which have been conducted underground during the past 12 months in connection with the application of stonedust. In the Final Report of the Royal Commission on Accidents in Mines (1886) certain precautions are recommended, and the concluding paragraph states that— “ The observation recently made in Germany, in some preliminary expei iments, that a thin layer of fine angular sand strewn over minedust appeared to have the effect of preventing the communication of flame from a blown-out shot to all but the most inflammable dusts, is worthy of passing notice.” None of the witnesses who had given evidence before the 1891 Coaldust Commission tendered any informa- tion to the Mining Association Committee as to how stone or inert dust might be utilised as an antidote to the coaldust danger. Most of the witnesses, including Dr. W. N. Atkinson and Mr. J. B. Atkinson, continued to advocate the application of water on coaldust roads. No action to compel colliery owners to use either watering or zones was taken by the Home Offi e, even after serious explosions had occurred, and when it was known that coaldust had greatly increased the death roll. Such was the state of affairs in the early part of 1908—a period of 17 years after the publication of the Royal Commission report in 1891, during which time no practical antidote for the danger of coaldust had been offered to the mining world by engineer, chemist or other scientist. The author then recalls the experiment on July 18, 1908, in the experimental gallery at Altofts, which was the first occasion on which the principle was adopted of presenting specially prepared stonedust to the flame of a coaldust explosion. Briefly, the experiments of the Mining Association were the first to demonstrate— 1. That coaldust was explosive without the presence of inflammable gas (May 30, 1908). 2. That dustless zones were ineffectual (June 15, 1908). 3. That fine stonedust would extinguish an explosive flame (July 18,1908). It may be mentioned that the effect of fine stonedust on the flame of an explosion is in accordance with the opinion expressed by the writer at the coroner’s inquest after the Altofts explosion in 1886, when, for the first time in the history of mining, the verdict of a jury was that the men had been killed by an explosion of coal- dust free from an admixture of explosive gas. The writer was so convinced, after the experiments in 1908, of the efficacy of fine stonedust that he has felt justified in having stonedust applied to more than 20 miles of underground roadways in collieries with which he is connected. At the present time those colliery owners and officials who have witnessed the stonedust demon- strations, and seen the application of the same inert dust on the underground roadways during the past four years, consider the present position of the mine to be secure from a coaldust explosion. At the present time there are roads in coalmines quite as safe as those in metalliferous mines, since 10 lb. or more of fine stonedust have been distributed for every pound of coaldust, resting on the sides of the roadway and on the tops of the timbers—a quantity much in excess of the mixture of 1 lb. of stonedust with 1 lb. of coaldust which experiments in the gallery proved to be sufficient to prevent an explosion. Ooaldust has been successfully dealt with for the past four years by dislodging it by fine stonedust from the ledges and pockets, as well as from the surface of the sides of the roadways, and the tops of timbers. Con- sequently coaldust roads are no longer dreaded ; they are simply regarded as a danger which ordinary pre- cautions may avert or safely deal with, in the same way that the workings are kept free from water or accumula- tions of firedamp. It may be remarked that the ordinary velocity of the ventilating current does not take away the efficacy of the stonedust remedy, and if a proper method of stone- dusting be adopted, there should always be a reserve or excess of stonedust sufficient to dilute the coaldust. In his presidential address of 1912 certain additional facts were given by the author, which further confirmed previous statements regarding the explosive character of coaldust and the efficiency of fine stonedust in extin- guishing flame. The experience of the past 12 months has confirmed the correctness of the suggestions and observations stated in that address, especially as regards the various methods of applying the stonedust that have been tried during the past four years. The method most successful is distribution by hand, as by this means the dust can be better directed, and that with requisite force to dislodge the coaldust, and replace it by stonedust. To make more explicit the further experimental methods which have been conducted underground during the last 12 months, the writer submits the following answers to hypothetical questions:— Question No. 1: “Is an underground roadway safe from an explosion if after being stonedusted it becomes again covered with a layer of coaldust ? ” Experiments were made on certain underground intake roadways to obtain increased velocities of air-current from a normal speed to one of 5,000 ft. per minute. It was found * From a paper read before the Institution of Mining Engineers. stonedust underground would be 35s. in a flat mine. The total cost, therefore, of keeping such mines efficiently stonedusted would be less than T^d. per ton of coal produced, or an annual cost of about £200. During the past four years the cleaning up of the stonedust has been done in the ordinary work of keeping the roads clear for haulage purposes, and the stonedust has been pulverised in an ordinary pug mill. In conclusion, the writer wishes to repeat what he stated at Nottingham in January last, that the time has now arrived to apply in practice what has been success- fully proved by experiment. Experience has shown that fine stonedust possesses those qualities which are essential in a preventive for a coaldust danger—namely, that it does not introduce any new form of danger, is universally adaptable, can be supplied at a low cost, and has on all occasions proved to be effective. It should be looked upon as a n?cessary precaution in the same way that ventilation is adequately maintained to dilute and carry off noxious gases, that pumps are maintained to prevent the flooding of the mine, and that timbering is carried out to guard against falls of roof. In the process of time precautions against the danger of coaldust will be looked upon as part of the ordinary routine of the mine. If these precautions are carried out, then the writer believes that coalmines will be made safer than ever before. that at a velocity of less than 1,500 ft. per minute, ordinary dry coaldust was not disturbed, but that | at a greater rate the coaldust was raised and carried ’ away as a cloud in air. Stonedust, however, was not disturbed, until the velocity reached 2,600 ft. per minute, above which speed it was carried away by the air- current as a cloud. A velocity of 2,600 ft. per minute is equal to 29’5 miles per hour. In the Altofts experimental gallery one of the lowest velocities recorded as the speed at which an explosion travelled was 120 miles per hour, or four times faster than the air-current which has been found necessary to raise stonedust and coaldust as a cloud. The recorded rate of travel of some of the more violent explosions in the gallery was 300 miles, and in one particular explosion 1,300 miles per hour. Hence it will be understood that even if there were a layer of coaldust overlying the stonedust on an underground roadway, the whole of the dust present would be raised by the “pioneering wave” of an explosion. Judging from the records obtained at the experimental gallery, the explosion would be stopped and the further produc- tion of poisonous gases in the roadways prevented, provided that the percentage of stonedust was not less than that suggested. Question No. 2: “ Can stonedust be applied to all places where the coaldust is liable to be deposited ? ” During these experiments stonedust has been thrown by hand to dislodge the accumulations of coaldust resting on the roof timbers and to replace them by stonedust. The stonedust-laden air current distributes the dust on the roof ti mbers and in the interstices of the mine. When settled the bulk of the stonedust will remain in position harmlessly resting on the strata ready for use. As an example of how stonedust may be carried on an air current, 2| tons of stonedust were placed on a main intake road along which 90,000 cubic feet of air were passing per minute. A jet of compressed air was introduced into the heap of stonedust to raise the dust in the air current. The heavier dust settled in the first 600 ft., but the lighter dust was carried for a distance of two miles, a larger proportion settling on the roof than on the floor. Question No. 3: “ What quantity of stonedust is it necessary to use on a roadway in which there is a thick deposit of fine coaldust ? ” As already suggested, first dislodge the coaldust and replace it with stonedust. The road is now treated with a heavy dressing of stonedust, the quantity varying with the size of the road. As any excess of stonedust increases the margin or factor of safety, it is a cheap form of insurance against explo- sions. An average first dressing at Alrofts is 2 cwt. per lineal yard, as it has been found in practice more economical to apply heavy dressings at longer intervals than light ones at shorter intervals. The principle which has been constantly kept in view has been to preserve the same grey appearance on the roadways as the return airways of the Silkstone pit were known to have had before and after the explosion in 1886. The first dressing, when the proportion of coaldust present was large, was a quantity of stonedust in the proportion of, say, 4 to 1; but, as the additional dressings of stone- dust have been added to the earlier dressings, the percentage of coaldust has in consequence been reduced until there are on some roads as much as 20 of stone- dust to 1 of coaldust. No regular practice is made of analysing the proportion of dust present, but when it is thought necessary analyses are made. Question No. 4 : “ What is the best kind of inert dust to use ? ” The opininion expressed by Dr, Haldane, the investigations by Dr. Beattie, and the microscopical examinations show that the best material, from the physiological standpoint, is soft shale as free as possible from crystalline silica. Neither coaldust nor stonedust affect the general health of the miner, and each may be regarded as equally harmless. In addition to the opinions expressed by scientists, it may be stated that the men working in the stone for the past 30 years are equal in health and robustness to the men who have been working in the coal. Stonedust by reason of its light-grey colour readily shows any fresh deposit of coaldust. Its greater weight and its binding qualities allow it to be thrown in such a way as to displace coaldust from the ledges on which it rests, which lighter inert dusts are incapable of doing. So long as a large proportion of the dust is sufficiently finely pulverised, as already shown, the slightly greater weight is not detrimental, as both stone and coal dusts are easily raised by air currents of velocities far lower than those of the slowest explosive blasts. Stonedust has a steep angle of repose, and owing to its clinging qualities it adheres to vertical surfaces. Fluedust does not possess these advantages; owing to its lightness and its shape it does not bind so well in the hand, it does not displace coaldust from the sides and ledges, and in consequence of its darker colour it is difficult to tell what proportion of coaldust is mixed with it, and there have been strong complaints, from the men at Altofts who have had to deal with it, of its effects on the eyes, nose and throat. As stated last year, it is not a healthy dust to breathe, and if it were introduced in the underground roadways before it has been tested by Dr. Beattie (who the writer suggests should make similar experiments to those he made with stone- dust), and before further experiments as to its suita- bility have been made, it might cause considerable inconvenience. Question No. 5: “ What would be the cost of pre- paring the stonedust ? ” Including depreciation, repairs of plant, power and labour, the cost of pulverising the dust has been ascertained to be about 2s. per ton. Twenty tons of dust per week are sufficient for a large colliery raising over half-a-million tons of coal a year, working four seams—some of the coal faces 2§ miles distant from the winding shaft—or say £2 per week for preparing the dust. The cost of applying 20 tons of THE SLOW COMBUSTION OF COALDUST ANO ITS THERMAL VALUE * By F. E. E. Lamplough, M.A., and A. Muriel Hill, B.Sc. The investigations described were undertaken, in connection with the experimental work of the Doncaster Coalowners’ Committee, to elucidate to some extent the nature of the chemical changes involved in the slow combustion of coaldust, and to determine if possible the value of the heat changes accompanying the oxidation of different varieties of coal. Work on the subject was commenced in July 1912, and attempts were first made to determine quantitatively the course of the oxidation which occurred in coaldust maintained at a temperature of 110 degs. Cent, in electric heaters. In September, Dr. Haldane suggested that if the difficulties involved in the determination of the thermal effect accompanying oxidation could be overcome successfully, the investigation would be of considerable practical value, and at the same time would throw important light on the problem under consideration. Financial assistance was promised by the Doncaster Coalowners’ Committee, and work in this direction was at once commenced. Experimental Method.—The evolution of heat was measured by carrying out the oxidation of coaldust in a vacuum flask immersed in a water bath of regulated temperature. A sensitive thermo-electric method was used to record and measure continuously the tempera- ture of the coaldust. The absorption of oxygen was determined by recording the fall in pressure continuously by specially-devised apparatus. Analyses were made at the beginning and end of the experiment to correct for the carbon dioxide developed and for the evolution of methane, &c. The experimental details and diagrams will be included in the paper as finally published. Experimental Results.—The coals experimented with were obtained from different localities. Some samples from the Bullhurst seam were kindly sent by Mr. A. M. Henshaw. Other samples of coal were supplied by the- Doncaster Coalowners’ Committee. Numerous experi- ments were carried out before it was possible to overcome- all the difficulties of working with the elaborate apparatus, and to make the method suitable for a reliable quantitative measurement of the heat produced during the absorption of a known volume of oxygen ; but in all these preliminary experiments the results were qualitatively the same, and it was obvious early in the work that there was a close connection between the evolution of heat and the absorption of oxygen. Table I. is a summary of the results of reliable experi- ments obtained with the final form of the apparatus. In no case does heating take place without absorption of oxygen, and, conversely, absorption of oxygen is always- attended by heating of the coal. These two processes are obviously very intimately connected, and, taking into account the very different qualities of coal examined,, the numbers in the last column, which give the amounts of heat evolved during the absorption of 1 cubic centi- metre of oxygen, are surprisingly concordant. The mean value obtained is 3’4 calories per cubic centimetre of dry oxygen measured at 0 deg. Cent. When carbon is burnt to carbon monoxide and to carbon dioxide, the respective amounts of heat liberated are 2’6 and 4’4 calories during the consumption of 1 cubic centimetre of oxygen. All the samples, with the exception of anthracite, Bullhurst, and iron pyrites, were from the Barnsley seam. In the case of “ top softs” a sample of gas was taken during the progress of the experiment, and using the analysis of this sample, calculations were made of the thermal value of the absorption which occurred during two periods—the first six hours and the following 17 hours of the experiment. It will be seen that the values in the two parts of the experiment were nearly the same. An experiment was made with a sample of pyrites occurring in coal. The material was collected from the coal thrown away during unloading in a large coalyardr and the sample was apparently free from carbonaceous matter. The thermal value of the total chemical changes taking place during the oxidation of pyrites proved to be very dose to the value given for the oxida- * From a paper read before the Institution of Mining Engineers.