Vol. CV. THE COLLIERY GUARDIAN AND JOURNAL OF THE COAL AND IRON TRADES. ERID AY, JUNE 20, 1913. No. 2738. DEVELOPMENT OF COALDUST EXPLOSIONS. Fourth Report of the Explosions in Mines Committee. The following is the fourth Report to the Secretary of State for the Home Department upon the enquiry now being conducted at the Experimental Station at Eskmeals. The Report contains certain preliminary observations on the progressive development of a coaldust explosion as it travels along a gallery, and on the effects due to obstructions in its path. The Report is signed by the following members of the Explosions in Mines Committee:—Sir Henry Cunynghame, Mr. R. A. S. Redmayne, Oapt. A. P. H. Desborough, Prof. H. B. Dixon, and Mr. W. C. Blackett. The following is the text of the Report:— On Coaldust (Explosions. As it is our main intention in this Report to describe some of the phenomena that occur during the explosive combustion of mixtures of coaldust and air, such as take place in what are commonly called “ coaldust explosions,” it is necessary to consider briefly the conditions under which such explosions can be generated. At the outset it seems desirable, to avoid misunder- standings, to state what we mean by “ inflammation ” and “ explosion ” of coaldust. Although in the combustion of gaseous mixtures there is no well-defined border line between inflammation and explosion, the different terms being employed merely to indicate differences in the rapidity of combustion,* yet in the combustion of mixtures of coaldust and air it appears possible, and indeed necessary, to draw a line of distinction between an inflammation and explosive combustion. Put briefly, our view is that during an inflammation of coaldust (at all events from bituminous coals) the flame is propagated largely by the burning of gases distilled from the dust; whereas during explosive combustion the portion of each dust particle that aids in propagating the flame is burned as a whole, both the volatile matter and the fixed carbon being consumed. Fundamentally there appears to be no reason why the inflammation of mixtures of combustible dust and air should not produce results of the same nature as those observed during the inflammation of gaseous mixtures, for in both cases the phenomena are the results of rapid combustion. The more finely divided the combustible dust, the more nearly does it approach to the condition of a gas or vapour, and, if of sufficient lightness to remain in suspension in the air and thus form an intimate mixture with the air, there seems to be no reason why a flame once started in such a mixture should not be propagated throughout its extent—it being presumed that the dust can be inflamed readily. In making comparison, however, between the combus- tion of a gas, such as methane, and the combustion of particles of coaldust, the great difference in size of gaseous molecules compared with that of dust particles must be borne in mind. If it be assumed, for example, that a coaldust particle has a diameter of to’oo mra-> this is over 3,000 times the computed diameter' of a molecule of oxygen. Moreover, gas molecules are always in very rapid motion, the mean speed of oxygen molecules at ordinary temperature and pressure being about 425 metres per second. Compared with this speed, that of the floating dust particle is inappreciable. A dust particle floating among oxygen molecules might, perhaps, be compared to a balloon lashed by a storm of hailstones. Despite the difference in size of the reacting bodies, however, there are several analogies that may be drawn between explosions of gaseous mixtures and of mixtures of a combustible dust and air. As in the case of gaseous mixtures, there will be a definite ignition-temperature for each kind of dust and air mixture, and inflammation will not be propa- gated unless and until each successive “ layer ” of the mixture has been raised to that ignition-temperature. Similarly, there will be a “lower limit ” as regards the quantity of any given dust that must be in suspension in the air to enable self-propagation of flame to take place. The Propagation of Inflammation. When considering the question of the propagation of the initial inflammation of coaldust the nature of the means of ignition must not be overlooked. If a previously-formed dust cloud in the air be presumed it can be taken for granted, on a priori grounds, that, once ignition of a sufficient volume of the cloud has been * The “ explosion wave ” in gases—the most rapid form of combustion—-is, however, of a different character from ordinary combustion. The rate of travel of the explosion wave is a definite physical constant for any particular mixture of gases in which it can be set up. Fortunately, it does not appear possible to set up the explosion wave in mixtures of firedamp and air—or of coaldust and air. effected—no matter by what means—propagation of inflammation will take place throughout the cloud if the fineness of the dust, the quantity of dust in suspension, and the ignition temperature of the dust are suitable. In a mine explosion, however, a dust cloud does not necessarily exist ready formed; but the cause of inflam- mation has, in most cases, to produce the dust cloud I simultaneously by disturbance of the air. In such cases, | therefore, where the dust is not already in suspension in the air, both flame and concussion are necessary for the initiation of more than a purely local inflammation. For the propagation of inflammation in a mine, therefore, it appears to be essential either that (1) a ready-formed dense cloud should be present for a considerable distance along the roadway ; or that (2) the source of heat that causes ignition should also create a I disturbance of the air and thus raise in suspension ! deposited dust. When inflammation occursand the flame | proceeds along a gallery, the expansion of the gaseous ' products of combustion causes a movement of a column j of air which is pushed forward in front of the flame. ! The opposition to this movement may be approximately j calculated for a smooth gallery, since it depends on the inertia of the air to be moved, or the velocity of the air I pushed forward, and on the size of the tube. But in the roadway of a mine this opposition may be enormously increased by irregularities and obstructions which cause waves and eddies in the air. A cloud of dust in air so compressed and disturbed burns with greater rapidity than in still air. The effect on the intensity of the advancing flame is thus cumulative. It may therefore be the case that after- the flame has pro- ceeded a certain distance in the ready-formed dust cloud, the column of air driven in front of the flame is capable of raising the dust lying on the floor and other surfaces, and so creating an inflammable cloud, independently of any source of disturbance. This conception of the manner in which an inflammation of coaldust and air is capable of increasing in intensity and of propagating itself throughout any length of roadway containing at the outset dust merely deposited is due, we believe, to Mr. W. C. Blackett, who from a study of the conditions existing in the Seaham, Tudboe, Trim don Grange and Usworth Collieries, after the disastrous explosions that occurred, formulated his theory of a “ pioneering cloud.”* by the induction coil sparks at the nozzle. A large jet of flame was thus produced, from 10 to 14 feet long, and of about 1 ft. diameter at its widest part, resembling an ignited “ blower ” of firedamp.* No unburntj gas escaped into the gallery. A large flame of this nature (unaccompanied by concussion) was found capable of igniting a ready- formed cloud of coaldust, but was unable to effect the propagation of flame for- any considerable distance when the coaldust was simply placed in a heap in its path. It was therefore necessary to create beforehand a dust cloud over a certain distance, into which the flame from the igniter could be projected. This was effected by spreading the dust on thin horizontal boards, 6 in. wide and 12 ft. long, suspended from the roof of the gallery and extending end to end over a distance of 150 ft. from the igniter' towards the open end of the gallery. These boards, which hung about 8 in. below the roof of the gallery, were caused to fall simultaneously, at the same instant as the gas-flame was produced, by the release of electrically-controlled catches; and, after falling 6 in., still in a horizontal position, were suddenly jerked over sideways, so that the dust resting on them was projected Gas-Jet igniter Explosion lube Right-angle bend From Fan Fig. 1. OPEN END This theory was founded, as aforesaid, on practical experience obtained during the course of investigations made after colliery “ explosions.” It remained to be seen how far it was borne out by what takes place during experimental inflammations on a large scale. A number of experiments for the purpose of obtaining information on this question were made by Dr. Wheeler for the Mining Association in the Altofts gallery. The results, which are given below, have not hitherto been published. Arrangements were made by which dust clouds of different extent could be ignited by a large gas-flame, unaccompanied by any concussion. The general arrangement for these experiments is shown in fig. 1. The gallery (the Altofts gallery) consisted of a wrought iron tube 74 ft. in diameter and 600 ft. long. One end was open to the air and the other was joined, by means of a series of right angle bends to a fan. For a more detailed description of this gallery, the Record of the Mining Association should be consulted. The igniting arrangement is shown in fig. 2. It consisted of a vertical cylinder A of about 2 cubic feet capacity, fitted with a weighted piston B. This cylinder was filled with coal gas under a pressure of 20 lb. per square inch, the pressure being obtained by weighting the piston with lead discs C placed on a platform carried by the piston rod. An outlet tube from the bottom of the cylinder was bent upward at right angles and closed at the top by an electrically-controlled valve D. Beyond the valve the outlet tube was continued through the side of the gallery (as indicated in fig. 1), and ended in a 2 in. nozzle fixed centrally in the gallery and directed towards its open end. Just before an experi- ment, sparks from an induction coil were passed across the nozzle of the tube inside the gallery. When the valve on the cylinder was released, the weighted piston fell and forced out the coal gas which was then ignited * Vide “The Combustion of Oxygen and Coaldust in Mines,” Trans. Fed.Inst.Min.Eng., vol. 7, p. 54, 1894. See also Proceedings of the National Association of Colliery Managers. March 1891. Fig. 2. D into the air. In this manner a ready-formed dust cloud was produced extending 150 ft. Beyond this 150 ft. of previously formed cloud, the coaldust was simply deposited on the floor of the gallery over the distance remaining to its open end—namely, 350 ft. The coal- dust, which was obtained by pulverising Altofts Silkstone nut coal, was present throughout in quantity corre- sponding to 0'4 oz. per cubic foot of air-space.' A current of air, of insufficient velocity to disturb the dust deposited onjthe boards, was forced towards the open end of the gallery during each experiment. Three experiments were made in this manner. In one of them the flame travelled only 200 ft. from the point of ignition — that is to say, only 50 ft. beyond the distance over which the ready - formed dust cloud extended. In the other two experiments the flame travelled the whole length of the gallery, the average velocity over successive distances of 100 ft. slightly increasing, and issued 115 ft. out of the open end into the air. It is thus apparent that if an inflammation initiated without concussion takes place in a gallery along which for a certain distance a ready-formed dust cloud extends, sufficient force is developed at the end of this cloud to * After numerous trials it was found that with a 2 in. nozzle, and with the gas under a pressure in the cylinder of 20 lb. per square inch, immediate ignition by the induc- tion coil sparks was obtained when the valve was released. A smaller nozzle gave a longer flame, but ignition of the gas was uncertain.